Damselfish:The one hour rule was definitely in the PADI Nitrox class when I took it. Not that I've ever seen anyone worry about following it.
Perhaps you are thinking of the recommendation regarding oxygen exposure? That advice is in the nature of a loose guideline rather than a rule per se, and mainly applies if the diver's allowable exposure reaches 50%. The NOAA O2 exposure limits as adopted by PADI actually don't give any surface interval credit but rather just add all the exposure percentages up dive by dive over a 24-hour span. Regardless of the lack of SI credit, offgassing obviously does take place during surface intervals, and the longer those are, the more both the residual nitrogen and oxygen will dissipate, which can only be good for the diver. It's true that most recreational divers don't pay much attention to the oxygen exposure surface interval recommendation, probably because at recreational limits (in particular the MOD limits and no-deco diving limits), elevated percentages of O2 exposure are highly unusual.