As a rough guide, how many hours on CCR would you recommend someone to do before changing focus from CCR only to other styles?This is me. I dive my CCR on dives that make more sense on CCR. I dive OC on dives that it makes sense. They are both wonderful tools.
When switching to closed circuit, I recommend students switch to it 100% for the first year. Get the bugs worked out, get everything sorted where things become intuitive. At that point, pick the one that works best for what you are doing.
From my own experience, 100 hours is where I felt far more in control all the time. Prior to that there was a lot of "conscious competence" going on where it required active thought. Post that time it's far more "unconscious competence" where most things are automatic and don't need thinking about. This especially applies to buoyancy control.
Of course I was "in control" of my CCR way before 100 hours; by the end of my MOD1 it was OK. However, the unit would surprise me or just feel difficult; as if it was controlling me and I had to work hard to control it. Post 100 hours I've seen most of the "difficulties" and deal with them automatically, buoyancy is as good now as it was on open circuit (as measured by looking at my dive log graphs)
Aside from bailout practice, I actively shunned diving open circuit in my first two years of CCR. Now I just can't see the point of not diving CCR -- it's so flexible and nice to dive even on a recreational cattle boat for a ridiculously short dive swimming behind a DiveMaster!