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Ok, I am not speculating that it was bad air. That thought was mentioned in passing above, probably not seriously, but it's true that you don't know if you don't test yourself. It's not a common problem but only takes once, and I did feel a little silly testing with all of the zeros until I got my first 5ppm - and got excited once headed to a deep dive when we got 17! We turned the boat...Actually, if I were going to speculate on a cause just based on the meager details provided in the story, I would lean towards cardiac incident. Diver over 45, had incident at surface or while surfacing at end of a shallow, easy dive...but that is just pure speculation. A bad air incident would typically affect more than one diver on the boat and would happen earlier in the dive, not at the end. Hopefully we will eventually get more details or an update from Red Sail about the details of the incident.
To reply directly tho...
1: Yes, you can draw one bad tank alone from several; and
2: It's most likely to hit you on ascent when partial pressure of O2 decreases but CO is bound to red blood cells.
That's a real problem in that if you think something may be wrong, ascending makes it worse.
It's rare that you need your buddy to share air, but you still want him to be there with two second stages.