Why don't people notice their PPO2? That's the #1 mantra for diving a rebreather: Always know your PPO2
On OC, you always need to do a NoTox drill when switching regulators on OC. Plenty of failures with that as well as mis-analysing or mis-labelling gas.
At least on a box you ride it to the surface, continually adjusting the PPO2 as you go, no gas switching required.
Which is a training issue? Definitely an experience issue.
Arguably it's an issue when diving a full electronic CCR as you get more complacent that the computer will sort things out: if something's virtually always OK, you don't notice when it isn't. One hopes that people diving manual or hybrid rebreathers would be very aware of their PPO2.