No, not if you understand deco theory and do not just rely on what a computer is telling you. It's never a good idea not understanding what your computer is telling you and just follow it's instructions.
As far as the computer goes: why would you want to dive with a computer you clearly don't rely on? That's really dangerous. The danger of not following/relying on computer instructions and not having thorough knowledge of deco theory to do the math yourself is a recipe for trouble.
Let me rephrase: you aren't changing your risk of DCS by doing something to your computer. You're just saying you accept a higher risk of DCS in exchange for increased bottom time. Which is your call, but don't pretend you're doing something else.
If you have to ask whether changing the pO2 is the right thing to do, you probably shouldn't be doing it. I'm not saying it's a good idea at all--I'm saying that if you're going to fudge your computer without really understanding what you're doing, you might as well just drop the charade and add a few minutes to whatever it says. (Exactly: why would you want to dive with a computer you clearly don't rely on?)
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