First off I think it's a really bad idea to dive with two different tank set ups.
Why exactly? You have a buddy with large amounts of redundant gas. How is it a bad thing?
Is there any reason why your buddy chooses to dive with twinset?
Maybe he likes diving safely, not having to blindly rely on a 3rd party to get him out of trouble. Maybe he doesnt like having to switch tanks between dives so gets 2 or 3 out of his twins instead.
If the guy diving the twinset knows how to use them and can do his shutdown drills it shouldnt matter at all to someone diving with them beyond knowing which reg to grab to share gas should it be needed.