I'm only going by the info the diver provided in his posts and don't have the advantage of having talked to him, but from what I read, he had "a few dives" (profiles not specified) on his first diving day and did three unplanned decompression dives, one to 152 FSW, on his second diving day. His symptoms, as you pointed out, were relatively minor and his dive series was definitely provocative. There's no reason to believe that this incident had anything to do with a PFO.
PFO is associated with sudden-onset severe neurological DCS, inner ear DCS, and cutis marmorata, none of which the diver reported. Statistically he has about a 30% chance of having a PFO, so if he's tested and found to have one, it's very likely a red herring.
Duke Dive Medicine, and I as the author of the DDM posts, are not in the habit of second-guessing treating physicians who are onsite and have physically examined and diagnosed a patient. However, the diver's symptoms as described (circumoral/extremity paresthesia, headache and tremors) could also be attributed to mild tetrodotoxin poisoning, especially considering that he did not experience any relief during the first hyperbaric treatment. If this is indeed the case, then PFO is particularly irrelevant.
Best regards,
DDM