Diagnosis from afar is always fraught with danger - specifically the danger of completely missing the point.
But, in reading your post several things come to mind.The most likely issue here is that the Mares Bolt SLS is simply more positively buoyant than whatever jacket style BCD you have previously used. After all, the Bolt SLS is touted to be ' . . .Superbly Comfortable and Streamlined . . .', and that comfort is achieved in no small part by the inclusion of ' . . . Special Shoulder Pads . . . Longer, Pre-Shaped and Reinforced . . .', as well as the 'Lumbar Comfort System' that is included.. One price that a diver must pay for the extra (aka unnecessary) padding that provides that 'comfort' is the need to strap on extra lead. So, it is possible that your Bolt SLS is simply more buoyant than your jacket, and you need to add more weight to achieve / maintain neutral buoyancy.The rolling to the right 'sounds' like it is a weight distribution issue, either a lack of symmetrical distribution of lead, or clipping something with negative buoyancy on the right side of the BCD. It may also be a reflection of something in the design of ther unti. But, I would defer comment on that to others who may have first hand experience with the BCD.
The 'head goes up' issue is probably more straightforward. The primary weight pockets on the Bolt SLS are, like so many wight-integrated BCDs, placed in a position that is lower than your physiologic center of lift (your thorax). Underwater, your center of lift and center of weight seek vertical alignment. The majority of your weight is low (only 4 pounds in the trim pockets as I read your post). Plus, the bungee cord on the (huge, 46 lb) wing quite possibly pushes whatever air is in the wing toward the top. The logical solution is to move more of the weight from the primary, waist level weight pockets, to the trim pockets (or even take 3-4 pounds out of the primary pockets and put a couple of ankle weights around your cylinder valve). Obviously, you will want to consider the fact that more of your weight will be non-ditchable in that case. But, it may help distribute the weight in such a way that horizontal trim is more readily achieved.