I'm voting for polyurethane just to be different. The good ones I had did work better in my MK10s, but I had a lot of bad ones, same batch as awap and couv. The short shelf like is a bummer. And to be honest I don't know nearly enough about the properties of each compound to make any meaningful comparison. I've read that viton has crummy abrasion characteristics, then I read in a different place that viton is good with abrasion. I've been told that polyurethane absorbs water, so that's probably not good, but maybe someone else will tell me tomorrow that it does not. Who knows...clearly if there were a compound that was substantially better than the rest, or if nitrile o-rings were not suitable for scuba use, we would not see the kind of varied o-ring composition we do in scuba use.
So, my real vote would be.....it doesn't matter, just use a high enough duro rating for the pressure differential.