That is a bad idea. Reserve valves have been obsolete for decades. They are mechanically complex and cause more problems than they prevent. Such valves are barely even available anymore and have to be special ordered if you can get them at all.
I don't understand why some divers are trying to over complicate a simple issue. Usually, this stems from being unclear on the basics, and attempting to compensate for doing one thing wrong by doing a bunch of other things wrong as well.
If you need extra gas when real redundancy isn't needed, like for a very long shallow dive, then sling a stage tank filled with bottom mix and use that first before your back tank(s). If you can't monitor your own tank pressure, then you shouldn't be diving at all, and no amount of extra equipment can possibly compensate for being mentally unfit. If you have a mechanical failure, then your buddy has your redundant gas. And if you need a higher level of redundancy than your buddy can provide then buy a real set of doubles with a proper isolation manifold and learn how to manage failures.
But setting up a ridiculous little "pony" tank as a mismatched set of independent doubles is the worst of all possible options. It's like showing up for a race wearing different sized shoes that you scrounged out of a dumpster. Maybe I'm just vain but I wouldn't be caught dead carrying a pony.