First off, I'm not looking to start a 1.4 vs 1.6 debate! The conventional wisdom of 1.2-1.4 for diving and 1.6 for deco is perfectly sound.
I've been poking around on this subject for a while now though, and what I can't find is how exactly the 1.4 idea came about. I know there are loads of cases of Ox Tox at 1.8 and above, and that it's known to be really insidious. There's a great anecdote in The Last Dive about a diver who thought 2.0+ was fine, he actually got away with it for a dozens of dives before it finally bit him and he didn't come back up.
Are there any documented cases in literature, or even just well known examples, where divers had a seizure somewhere below 1.6? Or has theory just advanced to the point where we can say that odds are, it will bite someone sooner or later?
I am not entirely sure what you are trying to get at with your question. Reason I say this is because your forgetting the time factor. Remember its your exposure duration in relation to the O2 level is that causing O2 toxicity. You can have an o2 tox diving 1.0 in theory. When I do 500min cave dives ill rack up 100%+ CNS sometimes and that is diving between 0.5-1.0 (almost never am above 1.0 unless I'm on deco)
Perfect example, my dive a couple days ago 92% CNS
So to answer your question where does the 1.4 idea come from, my thoughts were always because of time (I am just assuming this). If you look are "XYZ" agencies CNS clock you will see that as you increase the PPO2 your CNS starts to rack up exponentially, especially between 1.6-2.0 its actually pretty crazy quickly it can sky rocket at these PO2's. So I am assuming most adopted 1.4 as a reasonable balance that gives you lots of time to dive at 1.4 while still keeping a very low CNS. And then where does 1.6 on deco come from. Well same thing, it is a balance where you still get very effective deco off gassing but for your "average" technical diver your still not racking up crazy amounts of CNS. In addition if I remember correctly there were some papers also showing supporting evidence that CO2 and high CNS can be linked to O2 convulsions, hence when if your going to be on a high Po2 it is on deco where you are not on the "working" phase of the dive.
To answer your question about documented cases, well I am sure if you look there are cases, especially in the CC world. But as I mentioned earlier time plays just as much of factor as the Po2. So I don't know how relevant just looking only at the PO2 is. Not to over exaggerate but theory diving at 1.8 for 5min would be safer than diving at 1.2 for 500min.
For your question about biting someone sooner or later. Well that is almost impossible to say. Way to many uncontrolled "human body" variable to determine when someone will have an O2 tox incident.
On a side note and I think
@crofrog first started to elude to it was that running high Po2's is not necessarily always a good thing and I am not to sure why so many have this fixation with diving 1.6. Not to open up a can or worms but I do a lot of sub 150m diving and on deco I mostly just run 1.4. Alot of my dives end up with 300min+ of deco and if you run your dive plan through "XYZ" deco software you will see that running 1.4 on your unit only gives you maybe 15min more of deco vs. running 1.6 and doubling your CNS
Perfect example of a typical 180m dive I would do:
Running 1.4 for deco; Dive time 323min with 187% CNS
Exact same thing but running 1.6 on deco; Dive time 306min with 433% CNS
Save 17min of deco but racked up 246% more CNS. 17min more in the water for a dive like that in the grand scheme of things is nothing compared to the risk of O2 tox.