Boy, I really misread the title of this post. When I saw "A Dangerous Gas Mixture" I had assumed it was going to be a post about a dangerous gas mixture. A better title for this post would have been "Careless diver get's lucky - gives Darwin a miss for another day!"
he *did* check in the store. the isolator being shut off then opened changed the final reading.
AT THE STORE: not only did he only check the O2 at just one post, he must not have checked the pressure at all. If he HAD checked the pressure at the store he would have found the problem; either by 50/50 dumb luck in checking the pressure on the tank that wasn't filled completely, or by being reminded by the presence of a pressure gauge in one of his hands to check the isolator to make sure he knew whether he was reading the pressure in one tank or two.
AT THE DIVE SITE: he seemed confounded by the low reading on his SPG until his BUDDY suggested checking the isolator...his BUDDY had to suggest he check the isolator? Following any proper gear set-up protocol/checklist would have had the OP checking that both posts and the isolator were fully open well before the point that he was standing there with his hands on his hips, looking at his SPG thinking "huh?"
Also, I'm a bit concerned about what come across as the lack of a well thought-out dive plan:
"...the PSI went up to 1840 and my buddy and I figured that would be sufficient for one dive so we entered the water." At a minimum I would have liked to have read "We compared this to our planned dive and determined that 1840psi was well within the limits..." or even that "...we modified our plan to accomodate available gas." However I'm reading the OP as saying "we were planning on 'winging it' with full tanks, so we figured that 'winging it' with 1840psi was fine too."
Ultimately the diver and the diver alone is responsible for knowing exactly what is in his tanks - both mix and quantity. Yeah, some dope at the fill station was innattentive, but there were at least 6 or 7 specific points along the way where the OP would have caught the problem if he had followed a fairly simple, yet rigorous approach. However, even when he finally DID catch the problem he still ended up entering the water with an unknown mix. It could have just as easily ended up being a drastically hypoxic trimix if somehow the other cylinder was topped off with helium instead of air. Unlikely, of course, but no way to know for sure without analyzing.
To make matters even worse, the "buddy separation" in area that the OP admits was "tight and silty every where I went" could have been a huge problem if the gas in the tanks was actual some way-out-of-bounds mix.
Now, before I get crucified for slamming the OP, I know I am being a bit overly harsh but doing so to prove a point. As we're taught in tec and overhead training, an error chain in this type of diving is much shorter and much more likely to end very badly than in recreational diving. There's a certain level of rigor you follow on every dive - whether it's dive 50 or 500 or 5,000. You cut any corner and you are playing with your life. This time it was merely an inconvenience, but that wasn't for lack of trying on Darwin's part! Hell, if Darwin hadn't screwed with the OP's buddy's computer they might have been deeper than the MOD for a 42% mix before realizing there was a problem.
All that said, a genuine "thanks" to the OP for taking the time to share the story with us. Kudos for caring enough about your fellow divers to bare yourself so that we could learn from your experience.