A thing to remember, not all LDS's make a profit off air fills. ( I bet few do).
I live 300 miles "inland". A lot of divers that drive to the beach to dive for a weekend get their fills "at the beacH" or rent tanks there.
So there isn't a lot of local filling going on. THe part that is is prob half students for classes or dive masters/instructors. (zero profit and a loss if you consider it still cost time/labor/filters/electricity/overhead/etc.
Add to it the fact that here no one dives in the winter (for the most part), then the LDS has a compressor and bank system that is barely used except for 4 or so "warmer months". Yet that compressor and Storage Bank costs the same as for someone who uses it 365 days a year, like the Keys. So tank fills get itemized out at a higher cost. I don't get fussy over this because I don't have other good local choices and I'm thankful he's there doing fills.
I have been talking to 1 of my dive buddies and he may be interested in going in 1/2 for a comppressor which will cut the costs almost in 1/2 (except the filters and electricity) Now looking at $2.50 fills kinda makes it worth a 2nd look
Take a good look at your liability and coverage once you start doing fills for or with someone else.