In fact the quote straight from the SDI Instructor Guide is this: We have settled on the rule of thirds as the appropriate reserve volume for the purposes of this course. However, even though this would give a diver ample volume for most emergencies such as emergency decompression or losing up lines solo divers must still be configured with a complete redundant gas source to safely manage the unlikely event of catastrophic failure somewhere in our primary gas system. (Copyright credit to Scuba Diving International)
So is decompression taught as part of the solo diving course? If not, then why mention that among the reasons for 1/3's?
Unless it's along the lines of "since you're diving alone if you get entangled with no one to cut your free, you might exceed your NDL's." But in that case your gas plan is probably blown all to hell already...