@bardass
I can't find a single reference to a person experiencing symptoms such as the ones you describe with this lady, anywhere.
Some sort of odd placebo effect simply cannot be ruled out.
I suggest you do the following:
1- double blind study where the lady in question alternately dives a few tanks of air and a few tanks of nitrox, and reports her symptoms to a person who records them, that same person does not know which tank holds which blend.
2- In the event there is a definite statistical correlation to back up her claims the next step would be to have her dive a 22% blend, increasing the 02 percentage over a series of dives to determine at what level the symptoms begin, again doing this as a "double blind" study with the lady diver and the person recording any symptoms not knowing what she's actually breathing.
That way you can not only verify that her claims are real and valid but also determine at what level she can enjoy the benefits of nitrox without experiencing symptoms. I'm sort of surprised that a trimix and nitrox instructor wouldn't have thought of that.