Well, that misses some of the reasons many of us standardize on particular gases. That's different than the "why O2" question.
(1) If everyone has the same deco gas(es), it means we get to deco together. Since gas switches are probably the most dangerous part of a "tech dive", I know *I* (and all those I dive with) want to be together with the team for all the decompression. If one person shows up with 80% and another with O2, we're going to be doing our switches (and deco) apart. For some of us, that's a non-starter.
(2) Picking a small set of gases let's you minimize one of the variables in decompression (i.e. gas choice). This leads to a better understanding of how you personally deal with varying deco schedules. If you use different gases all the time, you don't get to build up that inventory of constrained experience.
(3) Standardizing on gases can allow you to standardize on decompression schedules (e.g. Ratio Deco). Again, that just means minimizing deco variables (you are now holding constant the type of ascent and gases used for a particular depth/BT combination). Doing so can help you hone in faster as to what works and doesn't work deco-wise for your personal physiology.
Those are just some of the reasons many of us choose NOT to vary what deco gases we use on a whim.
As to why O2, for me it mostly comes down to: (1) no inert component, (2) fitting in with other deeper deco gas choices, (3) standardization, (4) ease of access (no blending required), and (5) a good personal history with it.