JimLap's concerns should be taken to heart. Be careful. You're a brand new diver. The impact of a good instructor should not be discounted. Ideally, you'll have a bunch of dive buddies who are experienced in diving dry. That can help immensely. Depending on the mentoring involved, it may be even better than taking a formal drysuit class. That being said, I took a drysuit class locally and I found it worthwhile.
One of my buddies did just fine without taking the class...but he was surrounded by a bunch of people who had tons of drysuit experience. He also had 100+ dives in a wetsuit, great buoyancy, and spot-on horizontal trim. Your experience level is different. This will likely affect your learning curve on the drysuit. If the fit is not good with your suit (too baggy in the legs, in particular), you might be susceptible to trapping air in your feet. Inverted recovery is a critical skill to master in order to dive dry safely. This is even more of an issue with a drysuit that has attached boots, like yours.
I'd recommend doing a bunch of shallow dives (20 - 30 fsw) at La Jolla Shores. It's an ideal location to practice with the drysuit (flat, sandy bottom + easy entry/exit). That's the site where you were probably certified, so it should be familiar. There isn't much to see in the shallows, but it would be time well spent learning how to operate the drysuit. It can be helpful to study drysuit literature designed for a formal class. See if your buddies can set you up with this kind of material.
Please don't do any of your early drysuit dives off of a boat at a site like the Yukon. We don't want to be reading about you in the Accidents & Incidents forum.
On the Ebay auction page, there's no mention of the condition of the zipper. Presumably it's a back-zip. If it's not in good condition (bent teeth and/or leaking), it can cost a pretty penny to fix ($250-$300). Even a DIY fix will cost over $100 just for a replacement dry zipper.
Good luck with the suit...