21% nitrox and air are the same thing. O2 exposure will be the same. Depth isn't relevant. Not sure what you're asking
I'm pretty sure the Gekko doesn't track O2 or PPO2 while in 'Air' mode. That is the main difference in function between 'air' and 'nitrox' modes, aside from the obvious one of O2 percentage. In other words the PPO2 alarm doesn't work in air mode.