You could...
Its called inwater decompression, or ommitted deco procedure. It will help, sometimes. It depends how much deco the person blew off. Obviously, if a technical diver blew off over an hour or more of deco, did a polaris ascent, it isnt going to help him very much (he is most likely toast).
If a recreational diver omits a deco obligation based on what their computer is telling them (yes, I am assuming some things here), then yes, it would help...
Fast ascents are something that need to be avoided. Going back down and staying there for a safety stop is not going to have a significant effect on an embolism. If someone has symptoms of an air embolism after a fast ascent, they need to go to a chamber asap.