OK back to the original question, yes on land works to dial you in to approximately where you need to be. You want enough flash that the flash exposure is correct whether you are at the surface 100 feet deep or in the dark, without experience that can be hard to judge looking at the image and histogram in combination with ambient light. That's what testing on land does, if you are really close and the water is clear the exposure should be quite close. Take that setting underwater and start at maybe 1/125 if you're between ISO100 and 200 and take shots varying shutter speed until you get a nice deep blue. Only change ISO if your shutter speed gets too low or too high. If you change ISO vary flash power by the same amount - plus one stop of ISO.....change flash output down by one stop and vice versa. Limit your task loading on your first try or two - just stay at your selected aperture dial in the shutter speed and ISO if needed and start shooting - vary the shutter speed as required as ambient lighting changes as you get deeper, the sun starts getting low or a cloud comes over - etc. If you want to test your flash exposure dial up you shutter speed to max sync speed and see if your subject illumination still looks good from the flash, you may need to dial up power a bit if the visibility is low or if you are a bit further away.
The thing to remember at the same aperture and ISO and flash power the exposure you get on your subject remains the same IF the flash is the same distance from your subject, if you vary your distance you will need to change power. Shoot in RAW for flexibility if you blow highlights or under expose a little. The ambient light should have little impact on this as long as the ambient exposure for your subject is not to too high for your choice of ISO and shutter speed., which is unlikely unless you are snorkelling.
Of course if you are shooting macro with no ambient background to consider, just dial up the shutter speed to flash sync speed and adjust your exposure purely with flash at 1/250 f16 ISO100, ambient light won't be a problem, though you may need to stop down more especially if you are shallow to make a black background depending on how bright things are.