Wow, I think that would be very difficult to do. The diver would really have to be distracted to not notice that the hose is coming from the wrong side, and from below, instead of from the right and over the shoulder.
The fact that the pony reg should be attached to the tank, means even in a hurry the diver should notice that he's unstowing a reg. You don't unstow a reg on the left side of your gear and think it's a primary reg. Then, you still have the fact that the hose is coming from the wrong side and below.
I would be interested in reading the accident reports detailing the dead diver with a empty pony and full tank, do you know where I can find it?
Lastly, in my opinion, 6 cu ft is too small for an emergency supply. That panicked diver will be sucking down air, probably at a rate of 1 cu ft/min or faster. At that rate, on the surface, that 6 cu ft tank will last 6 minutes. At 90 feet, it will last a little over 1 minute. 19 cu ft is a very common size, and was a good choice.
While a pony takes practice, and I don't think it replaces an octo, the odds are it won't try to kill you or be dangerous. I've had one for three years and I haven't tried to use it as a primary yet. Practice with it, train with it, and you'll be fine.