Multiple gas slots are useful for single-gas users as a quick way to pick from their most often used mixes. 21, 32, and 36% will cover most areas. Just turn the old off / new on.
At the risk of derailing the thread, for NDL dives I leave them all enabled and just activate the one being used. No, this does not invalidate the NDL time. Search for past discussions if you disagree or just ignore this tip.
From the Shearwater Perdix 2 Recreational Manual chapter 7.2 Multi-Gas Example Dive, at pg. 32:
This is an example of displays that might be seen on a
multi-gas decompression dive in 3GasNX Mode.
Max Depth: 40 meters Bottom Gas: 28% O2
Bottom Time: 20 minutes Deco Gas: 50% O2
1. Gas Setup - Best practices include checking your
gas list before each dive. This screen is available in the
Nitrox Gases section of the System Setup menu.
All
gases that are turned on will be used to calculate the
decompression schedule. Turn off gases you are not
carrying. Note that the MOD displayed on this screen
will only impact the bottom gas (28% O2). Deco gases
are governed by Deco PPO2.
8. Gas Change -
All decompression predictions are
made assuming you will switch to the best available
gas on ascent. At 21m, the breathing gas turns yellow
indicating that a better breathing gas is available.
If the switch is not made, deco stop and time
information will be inaccurate.
(Emphasis provided.)