Metridium, you are fortunate in buying a new valve which is O2 clean. Otherwise, cleaning a used valve is not rocket science as USD's lawyers and the CGA would have you believe, but it's not quite a cakewalk either. Oh, you don't need a "clean" room, special gloves and a chef's hat, but you do have to somehow clean the gunk out of the valve parts, and replace the O rings with exact replacements made from Viton or equivalent.
A tank can be filled with detergent and glass marbles, and rolled on the lawn, then rinsed and air dried. A valve is totally different and unless you are doing several valves the hassle may not be worth it. Detergents like Joy or Simple Green are nearly useless in removing some greases, like silicone, from valves. The problem is that you cannot easily reach the internal parts with a brush or pipecleaner. Silicone laughs at attempts to soak in hot water and soap. You will notice this when you attempt to wash the stuff off your hands.
If you don't have an ultrasonic cleaner, the valve and valve parts must be soaked in a solvent. The very best solvent for this purpose is trichloroethane. Soaking for one minute will remove every trace of silicone, or any kind of grease. Unfortunately, trichlor is getting hard to find so a substitute may be needed. (See what I mean about a hassle?)--- Special O rings, now special sovent. That's not all. Some plastics may degrade in a solvent bath. If possible, these should be scrubbed in a water detergent bath unless you have pretested the plastic. Oh yes, you will need some expensive O2 grease like krytox or equivalent. The good news is that once you have gathered all the materials, completely disassembled the valve, the actual cleaning, rinsing and air drying takes about two minutes.
Here is an example of an alternative solvent advertised as O2 safe:
http://www.ensolv.com/
As I say, you are lucky.