First and foremost, after deciding on what settings you will use, is to know that camera in its housing like the back of your hand BEFORE you get to your dive destination.
Shoot everything in RAW then convert them to JPG in the Canon DPP (Digital Photo Professional) software that came with the camera. Have a large enough card for the large RAW files.
You have one custom setting on that camera (I believe) to save settings. Use it for your non-strobe shots.
-Flash off,
-non Macro setting,
-White balance on Auto or Underwater as it doesn't matter because you will adjust the white balance in the DPP program which is the major plus of RAW on non-strobe shots.
-Tv mode so you only have to set the shutter speed and the aperture will automatically correspond.
-Don't shoot slower than 1/80 or a moving subject may blur, ISO 100 (increase if needed).
For your macro strobe shots you can also use the Tv or Av modes but the M mode is best if you want to set both the shutter speed and aperture value.
-Flash on. Be prepared to change the settings and/or the intensity of the internal flash as needed.
-ISO 80
-1/250 shutter speed
-F5.0 or F5.6 as a happy medium
-Auto or daylight White Balance