Originally posted by jetblast00
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I'm sure you've seen helium balloons deflate a little and then sink back to the ground, if what was in them was still He, (or He and O2) it would still be lighter than the ambient air even with the lesser volume.
Actually what is left inside is still He. A balloon floats due to the archimedes principle which states that a body immersed in a fluid is buoyed up by a force equal to the weight of the displaced fluid. The principle applies to both floating and submerged bodies and to all fluids, i.e., liquids and gases. It explains not only the buoyancy of ships and other vessels in water but also the rise of a balloon in the air and the apparent loss of weight of objects underwater. If you use the gas law M=PVM/RT a10 inch balloon that weighs 1 gram containing .178 grams of He weighs 1.178 grams and displaces 1.29 grams of air giving you only .112 grams of lift. So once it has lost some of the He it will be negatively buoyant. These calculations are based on pure He so a balloon with less than pure He would weigh even more and have even less lift.