Whereas the others will go diving with it and emerge safety. In some places you dive with what you can get. If O2 supplies and boosters are lacking then its 80% or more diving.
Most sane people would opt for 80% in that situation.
Actually the reason 80% is almost never needed are way more complex than this. Especially in the ocean.
GUE/DIR people for the deeper dives will use 21/35 bottom mix (at least) and 50% as the first deco gas. It reduces rock bottom and gets you onto the deco gas sooner as well. And for short exposures with mostly fast tissue accumulation, along with the helium in the mix, the 50% makes perfect sense to eliminate the He fraction deeper than 20-30ft.
Only for the longer exposures would a second deco gas (100%) get added and this times on each gas will be roughly equal. So there is little or no need for massive quantities of shallow-ish deco gas per a Buhlmann schedule. Going from EAN50 at 70ft onto EAN80 at 30ft is just bringing along a second bottle for marginal benefit and by the time a 21/35 diver has ascended to 30ft on EAN50 the only gas left to eliminate is nitrogen anyway, most of the helium has already been eliminated.
If you can make 80% by PP you can obviously make 50%. So 40-80cf of 50% and 25cf (an AL40 filled to 2000psi) are sufficient for up to an hour of deco. Beyond that, its not too bad to carry an al80 of O2 filled to 2000psi (50cf). This pretty much covers the range of normoxic-ish trimix ocean diving. (100-240ft).
If you are doing real hypoxic trimmix diving (12/65 etc), you pretty much need a booster to handle the helium fraction anyway. So IMHO "most sane people" get 50% first, then lessor pressures of 100% aren't a big deal.
Those still diving "deeper" air or lighter trimixes frequently use EAN32 and EAN80 deco mixes but they are running completely different shaped profiles than those of use diving 21/35, 18/45 etc trimixes.