Forgot to mention that most shops will also charge you double to fill doubles, even if they are putting in the same volume of gas that would fill a large single tank.
Actually, I have NEVER been charged double (or triple or quad) with any of my rigs that use tanks smaller than 72CF each. Only on my rigs that have one tank independent, like the quad 20's which is really triple 20's with two regulator fittings and an independent single, have I been occasionally charged for two fills. Just like if it was a Single and a Pony.