There is a degree of truth th this--but only a degree.The closest I can find to a cite is Brian Morris's "Ascending from a dive":
(Ascending from a scuba dive, | deep stops, |ascent rates, |safety stops, | time limits, | and gas needed)
Overall it reads like he is advocating longer safety stops (also deeper stops but that's a different can of worms) based on that. Obviously, if it works that way, it only works up to a point, but it implies that "most efficient off-gassing" would take somewhat longer than "as soon as it's safe".
According to bubble theory, the free gas in the body (which is in the form of bubbles) will exit at differing rates depending upon bubble size. That is the primary theory behind deep stops--keep the bubbles small in accordance with Boyle's Law.
Remember, though that one of the first time bubbles were studied in regard to decompression was when the PADI tables were created, and the no stop times we based on research that included looking at bubble formation in the divers. They found that bubble formation varied dramatically from one individual to another. Some would have pretty much no bubbles, others seemingly bubbled it they thought about diving. A diver in a no stop dive should not have significant issues with bubble formation.
But those free gas bubbles are only a tiny percentage of the nitrogen in the tissues. In fact, as stated above, on a no stop dive, many divers won't have much of any at all. The vast majority of the gas is dissolved in the tissues and will be exchanged in relation to the pressure gradient between the tissues and the inspired breathing gas.