The odds are rather low, but it almost certainly has happened. The way it's most likely to happen, however, makes the risk of harm rather small.
Could an air diver be the unlucky recipient of a deadly mix when their tank gets mixed up with the deco tank I dropped off for a partial pressure blend of 80-90%? Yes, though their tank probably wouldn't be O2 clean and therefore wouldn't get filled, and even if it did the blender should (though hasn't always) stuck some kind of analysis on it that might warn them...but anything is possible. If they dove it, they'd probably tox shortly after passing 30'--if they didn't incinerate themselves before they even got in the water.
But a rich banked mix of 36%--which is the only real worst-case inadvertent EAN fill you could get--only gives you a pO2 of 1.78 at 130'. Is it beyond the 1.4/1.6 limit currently taught? Yes. Is it a pO2 that's basically right around where plently of people have and continue to dive air (with PSAI even offering a tech course on air down to 240')? Yes.
So, it's probably not going to happen, and even if it does happen the worst that's going to occur on a recreational dive is that you hit 1.7 and change in your pO2...which might very rarely kill you, but in general won't. And if you're diving air below 130', you should probably be making sure it's actually air. I check all my fills for CO, and any fill I'll be taking on a deco dive for O2%, including air.