Normally, my go to baselayer is the Norwegian Producer Devolds DUO active.
https://www.devold.com/en-gb/product-type/wool_tops/duo-active-woman-half-zip-neck/?color=951A
This is merino wool made with a thin inner layer of thermolite. Magic quality.
However, that being said. I have tried both "technical (ie plastic)" wicking layers and pure merino wool wicking layers. The pure merinolayers or devolds duoactive keep me warm and fuzzy. The plastic wicking layers feel constantly damp.
Disclaimer: I live in Norway, and summer diving is usually mid warm weather (25C) that will cause a sweat, and cold cave water (4C). Winter diving is the opposite. 0 to -10C air and -1 to 8C water.
I live in wool. Even in summertime my wool laundry is bigger than cotton. The only time I will be dressed in synthetics is pants and jogging in summer. (Oh and outer-wear)
My drysuit garments include different variations of the following depending on time and temp:
Wool knickers and bra
Wool Baselayer garments 1-2 layers depending on temperature
Heated vest
Kwark Navy or Navy Extreme undergarment depending on temperature
Wool neckliner
Wool undergloves 1-2 layers depending on temperature.
This will keep me happy as can be for 3.5hrs plus in a drysuit with water to my knees in 4C water.