jbd:
Can someone bring me up to speed on the math regarding volume and pressure when using a cascade set up?
The math below ignores the errors caused by the pressure-volume curve of air not being a perfect straight line.
You started with 444cubic feet at 4500psi in your bank. Since the internal volume of your bank stays contant, the pressure is just simply proportional to the amount of air in the tank.
If you remove 80 cubic feet (doesn't matter whether you blow it off to atmosphere or put it in another tank), then your tank will now have only 444-80 = 364 cubic feet and the pressure will be 364/444 * 4500 = 3689psi.
If you run the same math for the next tank, you will find that the pressure is less than 3000psi after you fill the 80 cu ft tank. The 80 cu ft tank doesn't hold 80 cu ft unless you are at 3000 psi, so you need a different method of calculating (Yes, I know that most 80 cu ft tanks are really 77.4, but I'm ignoring that).
4500psi is 4500/14.7 = 306 atm. The internal volume of the "444 cu ft tank" is 444/306=1.45 cu ft. The internal volume of a 80 cu ft at 3000psi tank is 0.392 cu ft (using the formula 80/3000*14.7).
Now lets hook up the two tanks. Pressure * Internal Volume stays constant if the amount of gas is constant. So lets see what happens when you effectively increase the size of the container from 1.45 cu ft to 1.45 + 0.392 cu ft.
3690psi * 1.45 cu ft = ?? * (1.45 + 0.392) Or ?? = 3690*1.45 / (1.45 + 0.392) = 2904psi.
Or you can just go find a gas calulator that does all this for you
Charlie
p.s. My first 3689 answer differs significantly from griffendm's 3960, but perhaps he meant 3690psi. Our second answer are within expected roundoff errors.