I don't understand this at all?
Take a look at your morning coffee. You dump a spoonful of sugar in it, stir, and the sugar seems to disappear. Coffee is a liquid, sugar is a solid, but what happens is that the sugar goes into solution: it ceases to be a solid and becomes part of the liquid.
The same happens with water and air. Leave a puddle of water around and eventually it will disappear. The water goes into solution with the air, it ceases to be a liquid and becomes a gas (water vapour). We call this evaporation.
Ditto with nitrogen and your blood stream. Nitrogen goes into solution, it ceases to be a gas and becomes part of the liquid. In all of those cases, there's certain factors that determine how much of a substance another substance can dissolve. Pressure is one factor, temperature is another. When a substance has dissolved as much of another substance as it can, we call that a saturated solution.
With a decrease in pressure or a decrease in temperature, a saturated solution can't be sustained any more. Whatever is dissolved wants to come out of solution and go back to its original phase. That's where clouds and fog comes from: the dissolved water vapour in the air can't be sustained any more because air pressure dropped (low pressure system moving in) or the temperature dropped. Water comes out of solution, forms water droplets, you get clouds and fog.
The same happens with nitrogen in your blood. It's not a gas that gets decompressed and thus becomes problematic, because there is no gas. The nitrogen is in solution and part of the liquid blood. The blood gets decompressed and that's what causes the nitrogen to want to become gaseous again due to the loss in pressure.
Luckily that doesn't happen right away. Substances come out of solution easily when there's a nucleation point around, something that the substance can attach to. In air, there's lots of tiny dust particles that the water vapour can attach to and that's where it forms fog and clouds. In a carbonated drink (there's CO2 gas dissolved in a liquid) the nucleation points are usually on the surface of the containing can or glass. But not all of the substance comes out of solution right away. A carbonated drink is still sparkly when you drink it. With a lack of suitable nucleation points, the substance may not come out of solution at all. What you get is a super-saturated solution: more of the substance is dissolved than what the solvent would actually be able to hold under the current conditions.
That's what happens upon decompression from a dive in your blood. There's more nitrogen dissolved than your blood would normally be able to hold. It's a super-saturated solution. Fortunately there's no good nucleation points around, so the nitrogen stays in solution. The only points where it can come out of solution is in your lungs: you exhale it. That's off-gassing. However, if you decompress too quickly, the amount of super-saturation becomes too great and nitrogen starts coming out of solution without proper nucleation points. You've got DCS.