Brown, I analyzed this subject of lung content, etc about a year ago during discussion with some Israeli college student. There is more than enough nitrogen in the lungs to cause bends if the diver could stay down and deep long enough. Normally, the body carries about one liter of disolved nitrogen. Doubling this amount would constitute saturation at 33 feet, the no deco limit. The diver's lungs may contain up to four liters of nitrogen, more than enough to cause trouble.
I have seen bends develop after a tank dive which was preceded by several hours of deep free diving. Never the opposite. The freediver who contemplates a follow up SCUBA dive must compute repetitive dive status. Freediving after SCUBA is safe as far as my experience. Sawtooth and rectified diffusion do not apply to freedivers, or if it does, the effect would likely be quite small to vanishing. IMO, the frequency of pressure changes is just too slow to create the conditions for this phenomenon and that is the mathematical model for freediving deco hazards.