Yeah, I understand your line of thinking, but if you need that extra gas to be neutral, the only benefit of moving it from your wing to the suit is that its easier to dump the expanding gas from the suit on ascent. Other than that, it would be really nice to be able to shed the extra gas entirely, and less weight same volume is the only thing that's going to get the job done. The other thing about just forcing the extra air into your suit with bulkier undergarments is you have no control where the extra air is going to sit and entirely possible it might push your trim out of wack in the process. Plus, there's no such thing as bulk without warmth underwater. On the surface you could be looking for undergarments that are bulky but permeable to let some steam out and air through, but once you zip up your trilam, bulk is going to equal insulation.
Do you have any feel for the amount you're overweight? Switching to a pair of AL80s from a pair of HP100s will be the buoyancy equivalent of dropping 7.6 pounds of lead. You'd also be losing 47cuft of gas, which sounds like a pretty ****** tradeoff. Something tells me you're not 8 pounds heavier than neutral. I wonder if we can shed some weight elsewhere?
I quantified how much doubles are going to put me overweight by dialing in neutral with a single tank. I'm currently at 2 pounds of lead with current drysuit undergarments, single HP100, steel backplate, fully kitted out. Adding another 500psi HP100, a manifold and hardware, another 1st stage, and stainless tank bands will add about 7.2 pounds. Dropping the lead brings that to 5.2 over, switching from a steel backplate to an AL backplate should bring that down to 2 pounds overweight. Lets for a moment assume that's your target, that at 500psi you're sitting with sufficient air in the wing to lift those 2 excess pounds of weight.
What other options do we have to drop a couple pounds of negative buoyancy other than the tanks? Carbon fiber BP was mentioned, but that comes at a pretty hefty cost for only a .5 pound weight savings, but certainly on the table for discussion. Aluminum triglides and d-rings? Lighter backup lights or backup lights with the same weight and larger volume? Lighter primary light? Fins that are the same stiffness but less dense? Plastic waist buckle instead of stainless? Delrin spool vs aluminum? Point being, I'm wondering if you can shed that extra weight elsewhere instead of just moving the gas? What else do you have on you that is heavy metal that you can switch to aluminum or delrin?
I've got a set of spring scales for determining the negative buoyancy of objects underwater. Next time we're diving the same mudhole I could bring them with to see if any of your gear is more negative than you're expecting, and quantify it.