On that note I was thinking: I know *of* the 'caustic cocktail' that @TotDoc suggested but not much about it. Could the fluid from the lungs (due to SIPE/IPE for example), if exhaled into the rebreather, create a caustic cocktail? Or would you need a full flood?
Caustic cocktail is kind of its own animal here. Although it doesn't take a massive amount of water to make SOME caustic mixture in the loop, it's not like a few drops of water are going to absolutely kill anyone. When people have pulmonary edema from things like SIP/IPE, there's typically not a ton of water pouring out of the lungs. The problem is that the fluid in the lungs prevents gas exchange, and since you need that to live, it's a very bad thing. Frankly, if he really had SIP/IPE, a caustic wouldn't matter much - he's not going to be even MORE dead from the caustic.
When people think of a caustic, they typically think about a lot of fluid being involved, and kind of an explosive event. Minor caustic fluid collections can happen, though, generally from a leak somewhere in the system. For example, I had a small leak in the counterlung of my rebreather when I bought it used. It would get a small amount of fluid in there, and when I went head down, I would get a small amount of alkali fluid in the mouthpiece. Not enough to do any damage, but certainly enough for me to get a bad taste and know it had happened.
My point for bringing this up is that even though that small amount of fluid is very manageable, it's still potentially damaging if you aspirate it into your airway. Alkali fluids can cause local tissue damage, and can trigger laryngospasm that can block the upper airway. As it turns out, even clean water can do the same thing for some folks - but it can be worse if the material aspirated is caustic. Since it was said that it sounded like he was choking, this came to mind for me.
Have you ever taken a drink of something and had it go down the wrong pipe? Yeah - that's laryngospasm. It can range from mild to severe, and can be life threatening. In fact, continued struggle to breathe against a closed upper airway can even lead to edema in the lower airway. Not fun! Just not necessarily what happened here, either.
I've heard of the 'chokes' before but not in too much detail. Is there any easy to read (I mean, I don't need a picture-book but I'm hoping not to have to read through scientific studies) that you could recommend to learn more about it?
Pulmonary DCS (Chokes) Here's a basic description in only a few paragraphs. If he had a controlled ascent, it seems unlikely this was his problem.