Carrying a single bottle of 100% O2 is probably not a very good idea.
When I carry a single bottle, like this, it normally has EAN 50 in it. And then, I am normally wearing my twin tanks, as well.
This isn't "Nereas bashing day", but why do you believe carrying a single bottle of 02 is not a very good idea? Maybe you should be more specific about the particular dive you are using. Do you believe that 50% on a dive to 90' for 50 minutes (well within the range of your doubles) is better than using 100% for the deco? I am truly very interested in your rationale for using 50% as the best deco gas for this type of dive.