This sounds silly, but the very first time I put on scuba gear (in the shallow end of the pool), the instructor had to prompt me that it's OK to breathe underwater - I was instinctively holding my breath, despite having a full seat of gear on

once I was over that nothing was particularly hard, though I was apprehensive about taking my mask off first time I went in the sea, as I thought it'd sting my eyes like the (very chlorinated) pool water did. Turns out in the sea, despite the crud in the water, it didn't sting at all.