Thank you for your detailed response, I appreciate it. I see we are approaching the situation from slightly different angles.
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However, 316L stainless steel, when properly cleaned and maintained, is also widely recognized as suitable for oxygen environments. The key point is that stainless steel requires a sufficiently strong ignition source to sustain combustion. We employ numerous processes to mitigate these risks. Through proper design and strict oxygen cleaning procedures, 316L stainless steel components can operate safely even in high-oxygen environments.[...]
Absolutely, 316L is used in many industries for its desirable properties, including some oxygen applications. My main gripe with the SCUBA industry is that it is very difficult to compare it to other gas industries. Those often manage fleets of thousands of rental cylinders with strict protocols in place. In SCUBA, on the other hand, anyone can buy an oxygen cylinder, transfill whip, compressor, and start filling in their garage.
I believe the SCUBA industry, especially at the design stage, should approach things from a worst-case scenario. What happens if someone does everything wrong? Does the equipment guarantee disaster, or does it at least give them a fighting chance?
1. Ignition & Combustion Risk
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Our Solutions:
We implement a comprehensive cleaning process to ensure all components meet strict oxygen service standards:
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This is one of those areas where we clearly come from different angles. As a manufacturer, your procedures are correct. The issue with oxygen cleanliness is that it isn’t a one-off state, it must be continuously maintained. That “garage diver” comes to mind again. What happens if the cleanliness starts to deteriorate? Brass certainly doesn't guarantee a beneficial outcome. But I feel like the usage of stainless steel is shifting the balance slightly to the
"bad outcome" state of the scales. Both systems will fail catastrophically when things get bad enough. The physics of it make me come to the conclusion that 316L reaches that state slightly faster than brass.
For me, good design mitigates risks from a gas-flow perspective. Are critical areas exposed to high-velocity gas? Are soft parts and springs shielded from adiabatic heating, flow friction, and particle impacts? Does the surrounding area act as a heatsink? Sherwood’s KVAB valves are a classic example: the way the parts are arranged is nothing short of genius once you dig into it.
2. Material Degradation
Sources of Risk:
- Metal Oxidation: 316L stainless steel, with its excellent chromium oxide passivation layer, exhibits outstanding stability in ambient high-oxygen environments, without the dezincification or stress corrosion cracking seen in brass.
316L certainly has the edge mechanically; it is a wonderful material. However, I doubt dezincification in a gaseous high-oxygen environment is any real concern, I’ve never seen evidence of that. I would like to be shown wrong on this. Stress corrosion cracking in brass is also rare as far as I know. When SCC is mentioned, my first thoughts go to aluminium and then to stainless steel. Stainless is known to be susceptible to SCC in the presence of HCl, though obviously that should never happen with a regulator (Yet I know many "technicians" using muriatic acid...).
- Oxygen-Compatible Seals: FKM/Viton® O-rings are used. The high bond energy of the C-F bond (485 kJ/mol) provides excellent thermal stability and oxidation resistance, making it the industry-standard choice for high-pressure oxygen service.
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I usually dislike relying on branded products, but I’ve seen too many substandard O-rings. Viton is certainly not the only good FKM compound. Are there any verifiable ways to guarantee quality FKM if Viton isn’t specified?
- Currently, we only use FKM/Viton® seals and MCG111 silicone grease on certain specific models.
I’ve long thought SCUBA gear would be better off using only PFPE grease. Personally, I’m not the biggest fan of Christolube 111; there are better, if sometimes more expensive, alternatives. Wouldn’t it make sense to drop silicone grease completely from the line-up, even if cost is a factor? I think your gear would benefit from it.
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- System Design Philosophy: We adhere to the principle that “a clean gas supply is the first prerequisite for safety.” Oxygen-compatible regulator design can only be effective under clean gas supply conditions.
- Gas Handling & Monitoring:
We recommend using high-quality filters (combining coalescing filters, activated carbon, molecular sieves, etc.) between the gas source and regulator to remove oil mist, moisture, and particulates. The gas used in our regulator tests undergoes compression (with built-in compressor filtration) + condensation + separate filtration.
- Importance of Clean Gas Supply: Only with pure gas can the high-oxygen compatibility design of the regulator truly function.
I think this is where our perspectives diverge most clearly. You’re correct that a clean gas supply is the first prerequisite for safety; no debate there. Perhaps it’s unfair of me to introduce worst-case scenarios, but I do think about design more in terms of flow patterns and “hot spots”. Almost anything can be made oxygen-safe if flow velocities and adiabatic heating are tightly controlled.
A good design shifts the outcome in the "idiots" favor, so to speak.
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- Medical Oxygen Systems — 316L components are widely used in hospital central oxygen pipelines, ventilators, and anesthesia machines in direct contact with medical oxygen.
On the subject of medical oxygen systems, I don’t entirely agree. As far as I know, most use copper tubing, per BS EN 13348 or ASTM B819. Granted, these often operate at much lower pressures.
- Aerospace & NASA Applications — 316L stainless steel is explicitly approved for oxygen systems when proper cleaning standards are met (e.g., ASTM G93, NASA-STD-6001).
Regarding standards: ASTM G93 is a cleaning guide rather than an approval of materials. Most documents I’ve read stop short of prescribing specific materials, instead advising engineers to assess suitability for the intended task. ASTM G93 does provide detailed recommendations on cleaning stainless steel, that is correct. If that is an "endorsement", I'm not qualified to say.
NASA-STD-6001, at least in the version I know, focused on test setups and materials evaluation. It mostly referenced 304L. I see a new version was released in June 2025, so I may need to revisit that. If it makes more explicit material recommendations, I’ll be pleasantly surprised.