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Only if you regularly use at least two calibration gases. Let's get a raise of hands here, who always uses two different gases to check their analyzer's calibration (at least three if TMX)?The graph on page 7 actually shows why using 100% to calibrate is a good thing (reveals a failure mode).
You need at least two points to verify the linearity of the sensor. The greater the % the earlier you can detect the failure mode.
If you use just one calibration gas, your sole issue is linearity and correct response factor in the region between your calibration and your measurement. I could hardly care less if my analyzer hits a ceiling at 80% as long as I'm not using it to analyze anything above 40%. I'm a lot more concerned about linearity and correct response factor between 20.9% and 40%.