Even thought (I've caused) the thread to drift a bit from the original question, I really appreciate everyone's input. I've been rolling various thoughts around in my mind, making calculations, etc. -- but input from Scubaboard denizens is priceless. A person can figure and calculate all they want, but the voice of experience is a whole 'nother level.
Although I've got it figured out now, thanks to SB, it sure would have been helpful if I had really grasped what was going on with the AL80 in terms of buoying up the "aft" end as it emptied. Figuring that out really helped my trim, but even in my PPB AOW dive, when I was nose-diving like mad, it wasn't really mentioned specifically. Water under the bridge now, but perhaps another new diver will read this later and benefit.
DD, thanks for your thoughts on the larger single vs. doubles. These considerations just really came up on my most recent dive trip, as the result of a combination of learning gas planning (minimum gas/rock bottom), and making some deeper dives (Keys wrecks). While an AL80 will easily cover me for the actual dive, it does not really/barely allow for minimum gas, so my thoughts turned to how to carry more. I did carry a pony on some dives, but as it was rented I'm still thinking about how to go for future/my own gear.
TSandM, you make a good point about my buddy providing redundancy/gas for shallow reef dives, and I have been completely comfortable with that. I really have two separate considerations (beyond my original question, which I think I have a handle on now!). One is buying my own tank(s) for the dives I'm doing now in AL63s (either buy those or something else, or continue to rent). The other is tank(s) for deeper Keys dives (wrecks). It is for the latter that the idea of more/redundant gas/regs came into question. For both my buddy and me. I don't know that I'm planning to do a lot more of those particular dives... we'll see.
And it was just on this last trip that I finally got to experience diving with a steel tank (the LP95, which I don't think I could support in summer with no exposure protection, unless I change some things about my rig, which I may do). This is when my thoughts turned to the steel 72 as a possibility (sub for AL63 on shallow dives). I think it would work with my current rig (but maybe not without exposure protection.... I feel a lighter plate coming on). The LP95 was nice too, although not needed for shallower dives of only one hour (and I don't think I could get two dives out of it, but... maybe).
I like the shortness factor of the AL63, and the steel 72 has that as well.
It's been really nice to get some feedback on my thoughts, in addition to hearing what you all have to say. Thank you!

I don't really have a local dive community, so SB is it (and has been great)

(Tho, I did actually meet a ScubaBoarder on the dive boat last month - that was fun.)
Blue Sparkle