Someone that small might do well with a HP80; they're very short tanks. The 1st valve in your post is a convertible DIN/yoke valve and can be used with either DIN or yoke regulators. The 2nd is the deeper 300bar DIN (I assume) and cannot accept yoke tanks. In terms of pros/cons, there are no cons to the convertible valve IMO, only pros. The 300bar valve is not any stronger, nor is the connection any more secure. In fact, the valves themselves are reputedly a bit more fragile because the deeper opening typically leaves less metal surrounding, and they can get knocked out of round a bit easier. But in terms of real-world, if you're certain you're only using DIN regs on the tanks, there's probably no significant difference between the valves.
$200 for a HP100 that new is a really good deal, I'd jump on that regardless as long as you can make sure there's no serious corrosion in the tank. It only takes a peek with a light that can fit down in there.
Other possibilities for tanks for her would be AL63 (far nicer to use IMO than AL80s) or LP72s, which you can find used for $50 all over the place and are really fun tanks for someone that doesn't use a lot of air. You need to be able to get a 2475 PSI fill on the LP72 to get 72 cft, otherwise you're looking at about 65cft.