I dont recommend 80% for a deco gas, depending on the profile using 50% from 70 feet or 100% at 20 are preferable..Big-t-2538 once bubbled...
But what I do know is that once you extend the PO2 above 1.4 to 1.6 you run a severe risk of getting an ox tox hit.
From my quick math, if you are diving to 150' the MAX O2% you should have is 28.8%...that works out to a PO2 of 1.6 ATA. For 100', max O2% is 39.6%
Thus, you say you normally dive 32 to 34% O2....and you normall dive to 100ft...that's an avg PO2 of 1.37....now according to my IANTD EANx text...the maximum recreational limits for O2 exposure at that PO2 in 24 hours is 180min....if your doing more than 4 dives...I think you might have exceeded this.
Anyway, this is just what I learned in my basic EANx class through IANTD. I wouldn't exceed these limits...you might want to check into an IANTD class?
As for more of my illustrious theories, if you are going to be using an 80% mix for DECO, I believe DECO stops are done at a high PO2 in order to off-gas, and you would be having to DECO at (approximately) 33 ft. as opposed to (I believe) 20ft. with 100% O2. I think most of the tech divers are now steering away from 80% for that reason, and using 70% for a deeper stop, then switching to 100% O2 for their final stop....I'm sure someone will correct me if I'm wrong.
Anyway, I too am going to be looking in the direction of deeper dive before too long...it seems to be interesting to me, but I am going to be sure I get some good education and knowledge before I jump in feet first.
If you are running high CNS loads you are much better on 50%, the time differance on hangs between o2 and 50% overall are minor and you get out of the water with a much lower cns. this said I always carry 50%as a deco gas (even when on a ccr for deco bailout). oxygen is useless to carry since you can only use it at 20ft or above.. if all goes well I'll do my deco on 50% and switch to o2 (hung below the boat or staged)otherwise I just finish it on 50%. Using both gases does decrease the decompression obligation since you started decoing deeper.. o2 by itself is only a marginal gain.. 80% is only 1 stop deeper and shorter than the 20ft stop.. so you really don't gain on the deco