Almity,
Its wonderful that you are thinking about it. I'll echo some inputs that suggest you discuss the unit with your hubby during prep and afterwards. Many things have to be learned over (like bouyancy) so please don't become to alarmed if he looks a bit 'newbie' to you. As part of his course, RB specific rescue considerations should have been discussed, I'm sure he'd be happy to pass those on.
Beyond that I would like to impress that even though you may be on OC, he can not go solo diving. Solo diving in this context is anytime your buddy is not within an arms reach. Most of the nasty RB accidents the individual was alone, they may have had a buddy but not with him/her. Its very tempting to want to get away from the noisy bubble blowers, but not wise at this stage.
The other suggestion is talk with him, its hard enough to get guys to talk much but many of us will go on & on when talking about our dive gear and a recent training class. Talking will accomplish a few things, one provide you some confidence in RBs and that he is ok to do it, two inform you a bit (we guys like to show off our knowledge), and three, help solidify his knowledge from the recent training, which will help him.
Having had a recent incident during training, and the author of your book being my instructor, we found that over thinking the rescue and trying to be Rebreather specific was, in hindsight, not the best thing. The plain old, tried and true, basic diving first aid would have been best. Having buddies there to take care, tow me in, and look after me for a few hours is why I'm able to comfortably sit here and explain this. Oh, the incident was not RB related, I just happened to be on an RB when things got bad. I think you are doing wonderful and seem very commited to helping your hubby stay safe. Wish I could get my wife to take a bit more interest in how she would rescue me if I needed it; she's still afraid of the gear.