cliffdiver
Registered
Rick Murchison:Not only do we tend to "forget" to drink enough water when we're immersed in it all day, breathing dry scuba air tends to accelerate water loss from breathing, and diving in salt water (whose salinity is about three times that of our bodily fluids) will actually suck water out of you by osmosis through the skin (not much, but when you're already dehydrated it can be the straw that breaks the camel's back).
Rick
Unusual medical conditions aside, you certainly cannot lose any water through the skin via osmosis, regardless of the salinity of the water you're diving in. Your healthy skin is too good of a barrier for that to happen. However, everyone is very right with respect to the dehydrating effects of breathing scuba air.
Every time you breath, above or below the water's surface, your departing breath contains moisture (read: a little bit o' water). Above surface, you breath back in, and you get a little of that moisture back from the normal air. Beyond that, you drink to get the rest. Now, breathing off scuba, of course, means you expel a bit of moisture with each exhalation but don't replace one bit of it when you inhale that dry air. At the end of a dive, hundreds of net-moisture-loss breaths later, you emerge dehydrated.
It is amazing the degree to which dehydration can contribute to headaches. It is equally amazing the degree to which we should all be slugging back the fluids during SIs and after diving for the day. I cannot say this is why your buddy got his headache, but it is likely, at a minimum, that dehydration aggravated it if it didn't largely cause it.