Personally, pound for pound I think HP 100's are a better choice for doubles than double AL 80's and would be more likely to be encountered as the HP 100 and AL 80 tanks weigh the same.
That leaves you with 200 cu ft versus 154 plus 30 for the two single AL 80's (that only hold 77 cu ft each) plus 30 cu ft pony diver.
So...
..........................Doubles diver...................Single + pony diver
First dive..............100 + 100 (200)cu.ft. ..........77 + 30 (107)cu.ft.
Second dive..........50 + 50 (100)cu.ft. .............77 + 30 (107)cu.ft.
It looks like the advantage is still with the two single 80's plus pony, but it is not.
Practically speaking on dive one I enter the water with 3400 psi (rounded down from 3442 psi) and plan to be back on the boat with no less than 1700 psi. If I have a problem on dive one, I have lots of gas in reserve over 100 cu ft, a clear advantage on dive one. But it gets even better than that.
Assuming the buddy has an AL 80 and a 500 psi reserve, he or she has 64 cu ft available for the dive. That 64 cu ft equates to only 1100 psi used in the double 100's. So assuming an equal SAC I am getting out of the water after dive one with 2300 psi. (The irony here is that 2266 psi would in fact be the way too conservative thirds everyone is talking about - so diving thirds with doubles actually works on pretty fish dives with no loss of bottom time.)
On dive two, I start with 2300 psi (133 cu ft or 26 cu ft more than the AL 80 plus 30 buddy has total) and plan to end the dive with a reasonable reserve of 500 psi, which coincidentally happens to be 29 cu ft. (very close to the 30 cu ft pony). So 133-29 = 104 cu ft left for the dive, with a 29 cu ft reserve. Potentially lots more bottom time on dive 2 with a liberal reserve.
But again the AL 80 buddy has only 64 cu ft available so I am again ending the dive with a lot of reserve gas - about 69 cu ft total or 1187 psi. (and again 1133 would be 1/3rd of the original 3400 psi and 1150 psi would be half the 2300 psi I started dive 2 with, so on dive 2 I am actually diving halves - extremely conservative gas planning.)