Highly variable. In one experiment at 3.1 ATA O2, OxTox hits ranged from under 5 minutes exposure to over 160 minutes exposure. In other experiments it appears that the average time to a hit in 10% of the test subjects ran roughly along a straight line when PO2 and Time are both plotted by log, with the average time to hit at 1 minute at about 8.5 ATA and an average time of 100 minutes at about 1.8 ATA. But again, on an individual basis the numbers are highly variable, and the bottom line is that one should remain well within the established NOAA time limits and endeavor to remain below the recommended limiting PO2 of 1.4 ATA, and not even accidentally exceed the maximum limiting PO2 of 1.6.
Note that in a chamber where higher PO2's are routinely used, an occasional O2 hit is no big deal, but underwater it is almost always fatal.
Rick