This is the only one that I still don't see how you can know/estimate unless you already know the relationship between CNS and NDL time limits.
Again, there isn't a relationship between them other than time being a component used to derive the limit. That is the only way in which they are related. Quit trying to tie them together. You can far exceed your NDL without coming close to your CNS clock. Let's say you were to do a deco dive to 12m. On air your PO2 is .46. That's not even on a tracking table. In the example I posted prior, you can exceed your CNS while not exceeding your NDL (although as shown, it's not really feasible, and you wouldn't be running that type of profile in a recreational dive). Beyond the scope of a recreational dive, either one can exceed the other, ideally, you never exceed your CNS clock. At that point you are not only concerned about pulmonary oxygen toxicity, the percentage we've been talking about, but you also have to consider daily OTU's for repetitive diving. Again not recreational.
It's when you are trying to tie them together that you are confusing yourself. View them as completely independent limiting factors. You cannot derive a relationship between the two.
Like freewillow said, CNS toxicity is purely a function of the partial pressure of oxygen and time. This is why you can exceed your CNS limit in 45 minutes if you are breathing oxygen at 1.6 PO2. However, if your PO2 is 1.4, your time becomes 150 minutes. Your FO2 (fraction of inspired oxygen) and your depth are what derive PO2. It doesn't matter if you exceed your CNS by breathing 100% O2 at 6m, or some other FO2 at whatever depth that makes the gas have a PO2 of 1.6, your maximum exposure is still 45 minutes. Your NDL for that depth is irrelevant. Remember that it is a dose. Imagine that it is an oxygen pill. You can either take one large pill, or 4 small pills, but either way you're taking 100% of the dose. That's your CNS clock.
NDL is a function of depth, time, and inert gas loading. It's the inert gas loading that defines your decompression obligation. It is completely irrelevant when determining your dose of oxygen, you just want to make sure that your dose is less than 100%.
Your questions most definitely have real ramifications, however the conditions during which they would present themselves are far beyond recreational diving. And realistically at that point, there's a good component of voodoo involved as well. Daily limits are designed so that you can take a chamber ride, repetitive limits get lower and lower, yet people still exceed these on big dives, some divers easily take a PO2 of 2.0 without toxing. In the end, there is still a lot of unknown about oxygen's effects on the body, and current standards are really just best guesses based on empirical research, however there are always outliers that break the table.
In the end it keeps coming back to what was said earlier, at the recreational level, you are not doing anything that would bring you any risk from oxygen-related issues beyond exceeding your MOD, which you can do regardless of mixture. Hell, the MOD of air is 66m/218ft.