Okay, I am thoroughly confused.
Wibble says that "for recreational non-deco-limit nitrox, it doesn't need to be that accurate; a couple of percent either way probably won't matter."
In response, you produce a scenario in which you think you are breathing a normal nitrox mix (32%???) but are instead breathing 100%.
Are you saying that is an example of being "a couple percent either way"?
Just to make doubly certain of the point I made earlier...
When you check your Nitrox mix one of the reasons for this is the rare possibility that the gas is actually 100% due to a cock-up by the gas monkey. This has happened -- I heard it on the intarwebs, so it must be true.
The other cock-up by the aforesaid gas monkey is issuing the wrong mix. Giving you a tank of 50% or 80% (if I'm around) instead of the 32% you ordered.
None of those examples are within a couple of percent of what you'd be expecting.
I did say that a couple of percent either way doesn't matter. For example, you've ordered 32% for a 30m/100ft dive. If it comes back as 30% or 34% it doesn't matter. Your MOD (maximum operating depth) for 34% would be...
dose / mix = 1.4 / 0.34 = 4.1ATA = 31m/103ft
However, if it had been hit with the cock-up hammer and was full of 50%, then the MOD would be:
dose / mix =1.4/0.5 = 2.8ATA = 18m/60ft
Worse still the PPO2 at 30m would be:
pressureATA X mix = 4 x 0.5 =
2.0 PPO2
That is full on danger of hyperoxia (too much oxygen causing you to fit, passing out, drowning...).
It's you lot who dive the same looking ali80 tanks! In Europe we use steel cylinders for backgas and ali80s for deco/stages.
TL;DR
Always analyse your gas in case there's a serious problem with the mix.