I don't know if there is a standardized definition of service versus working pressure, but here is my definition:
Below is an example of a tank that has different service and working pressure:
- Service pressure is the pressure stamped on the tanks. It is the basic tank pressure use to do any tank calculations... it is used to figure out the tank hydro test pressure, etc.
- Working pressure would be the same as the service pressure unless it has an allowed overfilled "+" stamp on the cylinder. On some steel tanks (normally the 3AA type tanks) the tank can be filled to 10% over the service pressure as long as it has a current "+" stamp next to the most recent hydro test date.
72 cu ft Standard (vintage)
Service pressure: 2250 psi
Working pressure: 2475 psi (2250 psi +10%)
Actual air capacity: 71.2 ft3 (at a working pressure of 2475 psi)
Outer diameter: 6.9 in
Length without valve: 25.1 in
Empty weight: 26 lbs (w/o valve)
Buoyancy Empty: 0 lbs (w/valve)
Buoyancy Full: -5.4 lbs (w/valve)
When calculating SAC, what maters is that you know the actual air volume at whatever pressure it is specified.
For example in the steel 72 mentioned above:
At the working pressure of 2475 psi the actual volume is 71.2 cu ft.
At the service pressure of 2250 psi the actual volume is about 65 cu ft.
Either pair of numbers will give you the correct results as long as you use them together.
I actually looked this up last week. DOT does not define working pressure for scuba cylinders, they do for other types of gas storage stuff though. Hence its technically a 10% overfill of the service pressure.
Here were the definitions/citations I found:
49 CFR § 171.8 Definitions and abbreviations.
Working pressure for purposes of UN pressure receptacles, means the settled pressure of a compressed gas at a reference temperature of 15 °C (59 °F).
49 CFR § 173.301a Additional general requirements for shipment of specification cylinders.
(c) Cylinder pressure at 21 °C (70 °F). The pressure in a cylinder at 21 °C (70 °F) may not exceed the service pressure for which the cylinder is marked or designated, except as provided in §173.302a(b).