LD,
There's a lot more involved in using O2 at 20' than most divers know about -- surprise, surprise. Extended periods on O2 at 20' will give you a congested feeling in the chest/lungs, but this is easily dealt with by taking back gas breaks (use the lowest PPO2 mix available). However, there is more to it than congestion -- extended periods of O2 will actually restrict offgassing. The best way is to go on O2 for 12mins (not 20mins) and break for 6mins on backgas.
Why 12mins on and 6 mins off? Here's the science/reasoning as I understand it:
In 12 mins, O2 will reach its most effective and useful saturation level. Beyond that, O2 is actually detrimental to gas transfer. Longer exposures to O2 will constrict blood vessels in order to protect the lungs. This adds cells and mucous excretion which restricts gas transfer and causes lung tissue to swell and may possibly cause scarring and long term problems.
Why the break?
Going to a low PPO2 will prevent (or keeps to a minimum) and/or reverse all this gas restriction going on in the lungs. You want to avoid reversing the condition by preventing it from occurring in the first place (i.e. 12 mins on -- max). So, by going on a low PPO2 mix, you will reverse what ever restriction has occured and "reopen" the capilaries and thus allow gas to enter the blood (better offgassing). The deco programs out there cannot take these breaks into account -- they see them as being a bad thing. By going back and forth between O2 and backgas you are maximizing off gassing in the most efficient way possible.
This is the gist of it.
Mike